Alternative Marine Fuels: A Pathway to Carbon-Neutral Shipping
Amirulaminfirdaus Mohd Yusof · Corresponding Author
Faculty of Maritime Studies, Universiti Malaysia Terengganu
Correspondence: s65535@ocean.umt.edu.my
Abstract
Shipping decarbonization requires fuel-selection decisions that account for emissions across the full fuel lifecycle as well as machinery adaptation, economic feasibility, shipboard safety and bunkering availability. This study evaluates liquefied natural gas (LNG), methanol, ammonia, hydrogen and advanced biofuels using a seven-criterion weighted-sum multi-criteria decision analysis (MCDA), supported by a structured technical literature synthesis. Criteria are well-to-wake CO₂ reduction, NOₓ or SOₓ reduction, volumetric energy density, engine compatibility, fuel cost, operational safety and supply-chain maturity. Under the stated scenario inputs and weights, the ranking is advanced biofuels (0.752), LNG (0.669), methanol (0.655), ammonia (0.559) and hydrogen (0.539). The figures are reproduced from the declared input matrix, including fixed five-point denominators for qualitative scores. A five-scenario sensitivity analysis reveals that LNG ranks first if the weight on cost rises to 0.40, while advanced biofuels retain first place under the carbon- and safety-priority scenarios. These results are conditional decision scores rather than validated lifecycle emission factors or a fleet-wide fuel hierarchy. The evidence indicates that drop-in biofuels may support near-term deployment where credible feedstock certification is available; low-carbon methanol and hydrogen-derived fuels require expansion of renewable production and distribution; and LNG requires scrutiny of methane slip and upstream methane leakage. Fuel transitions should therefore be evaluated by verified pathway-specific well-to-wake emissions, ship operational profiles and risk controls rather than nominal fuel identity alone.
Acknowledgement
The author gratefully acknowledges Universiti Malaysia Terengganu (UMT) for its institutional support and for providing the facilities, resources, and conducive research environment necessary for the successful completion of this study.
Conflict of interest
No competing-interest declared
References
Alamoush, A. S., Dalaklis, D., Ballini, F., & Ölçer, A. I. (2023). Consolidating port decarbonisation implementation: Concept, pathways, barriers, solutions, and opportunities. Sustainability, 15(19), 14185. https://doi.org/10.3390/su151914185
Balci, G., Phan, T. T. N., Surucu-Balci, E., & Iris, Ç. (2024). A roadmap to alternative fuels for decarbonising shipping: The case of green ammonia. Research in Transportation Business & Management, 53, 101100. https://doi.org/10.1016/j.rtbm.2024.101100
Depken, J., Dyck, A., Roß, L., & Ehlers, S. (2022). Safety considerations of hydrogen application in shipping in comparison to LNG. Energies, 15(9), 3250. https://doi.org/10.3390/en15093250
DNV. (2023, March 30). Methanol as fuel heads for the mainstream in shipping. https://www.dnv.com/expert-story/maritime-impact/Methanol-as-fuel-heads-for-the-mainstream-in-shipping/
Duong, P. A., Kim, H. J., Ryu, B. R., & Kang, H. (2024). A quantitative risk analysis during truck-to-ship ammonia bunkering. Sustainability, 16(5), 2204. https://doi.org/10.3390/su16052204
Fullonton, A., Lea-Langton, A. R., Madugu, F., & Larkin, A. (2025). Green ammonia adoption in shipping: Opportunities and challenges across the fuel supply chain. Marine Policy, 171, 106444. https://doi.org/10.1016/j.marpol.2024.106444
Gartland, N., & Pruyn, J. (2022). Marine biofuels costs and emissions study for the European supply chain till 2030. Frontiers in Energy Research, 10, 894555. https://doi.org/10.3389/fenrg.2022.894555
Huang, J., Fan, H., Xu, X., & Liu, Z. (2022). Life cycle greenhouse gas emission assessment for using alternative marine fuels: A very large crude carrier (VLCC) case study. Journal of Marine Science and Engineering, 10(12), 1969. https://doi.org/10.3390/jmse10121969
International Maritime Organization. (2023). 2023 IMO strategy on reduction of GHG emissions from ships. https://www.imo.org/en/ourwork/environment/pages/2023-imo-strategy-on-reduction-of-ghg-emissions-from-ships.aspx
International Maritime Organization. (2024). 2024 guidelines on life cycle GHG intensity of marine fuels (Resolution MEPC.391[81]). https://www.imo.org/en/ourwork/environment/pages/lifecycle-ghg---carbon-intensity-guidelines.aspx
International Maritime Organization. (2025). Interim guidelines for the safety of ships using ammonia as fuel (MSC.1/Circ.1687). https://futurefuels.imo.org/wp-content/uploads/2025/10/MSC.1-Circ.1687-Interim-Guidelines-For-The-Safety-Of-Ships-Using-Ammonia-As-Fuel-Secretariat.pdf
Ishaq, H., & Crawford, C. (2024). Review of ammonia production and utilization: Enabling clean energy transition and net-zero climate targets. Energy Conversion and Management, 300, 117869. https://doi.org/10.1016/j.enconman.2023.117869
Ismail, A. M., Metwalli, M. M. A., & Alamoush, A. S. (2025). Towards safe maritime decarbonization: Safety barriers of methanol fuel. Sustainability, 17(11), 4896. https://doi.org/10.3390/su17114896
Karvounis, P., Dantas, J. L. D., Tsoumpris, C., & Theotokatos, G. (2022). Ship power plant decarbonisation using hybrid systems and ammonia fuel: A techno-economic-environmental analysis. Journal of Marine Science and Engineering, 10(11), 1675. https://doi.org/10.3390/jmse10111675
Klopott, M., Popek, M., & Urbanyi-Popiołek, I. (2023). Seaports’ role in ensuring the availability of alternative marine fuels—A multi-faceted analysis. Energies, 16(7), 3055. https://doi.org/10.3390/en16073055
Li, S., Tan, E. C. D., Dutta, A., Snowden-Swan, L. J., Thorson, M. R., Ramasamy, K. K., Bartling, A. W., Brasington, R., Kass, M. D., Zaimes, G. G., & Hawkins, T. R. (2022). Techno-economic analysis of sustainable biofuels for marine transportation. Environmental Science & Technology, 56(23), 17206–17214. https://doi.org/10.1021/acs.est.2c03960
Mallouppas, G., Ioannou, C., & Yfantis, E. A. (2022). A review of the latest trends in the use of green ammonia as an energy carrier in maritime industry. Energies, 15(4), 1453. https://doi.org/10.3390/en15041453
Masum, F. H., Zaimes, G. G., Tan, E. C., Li, S., Dutta, A., Ramasamy, K. K., & Hawkins, T. R. (2023). Comparing life-cycle emissions of biofuels for marine applications: Hydrothermal liquefaction of wet wastes, pyrolysis of wood, Fischer–Tropsch synthesis of landfill gas, and solvolysis of wood. Environmental Science & Technology, 57(34), 12701–12712. https://doi.org/10.1021/acs.est.3c00388
Nerheim, A. R., Æsøy, V., & Holmeset, F. T. (2021). Hydrogen as a maritime fuel—Can experiences with LNG be transferred to hydrogen systems? Journal of Marine Science and Engineering, 9(7), 743. https://doi.org/10.3390/jmse9070743
Nunes, L. J. R. (2025). Renewable methanol as an agent for the decarbonization of maritime logistic systems: A review. Future Transportation, 5(2), 54. https://doi.org/10.3390/futuretransp5020054
Rony, Z. I., Mofijur, M., Hasan, M. M., Rasul, M. G., Jahirul, M. I., Ahmed, S. F., Kalam, M. A., Badruddin, I. A., Khan, T. M. Y., & Show, P. L. (2023). Alternative fuels to reduce greenhouse gas emissions from marine transport and promote UN sustainable development goals. Fuel, 338, 127220. https://doi.org/10.1016/j.fuel.2022.127220
Ryu, B. R., Duong, P. A., Kim, J., Choi, S., Shin, J. W., Jung, J., & Kang, H. (2023). The effect of ventilation on the hazards of hydrogen release in enclosed areas of hydrogen-fueled ship. Journal of Marine Science and Engineering, 11(9), 1639. https://doi.org/10.3390/jmse11091639
Solakivi, T., Paimander, A., & Ojala, L. (2022). Cost competitiveness of alternative maritime fuels in the new regulatory framework. Transportation Research Part D: Transport and Environment, 113, 103500. https://doi.org/10.1016/j.trd.2022.103500
Stathatou, P. M., Bergeron, S., Fee, C., Jeffrey, P., Triantafyllou, M., & Gershenfeld, N. (2022). Towards decarbonization of shipping: Direct emissions and life cycle impacts from a biofuel trial aboard an ocean-going dry bulk vessel. Sustainable Energy & Fuels, 6(7), 1687–1697. https://doi.org/10.1039/D1SE01495A
Van Hoecke, L., Laffineur, L., Campe, R., Perreault, P., Verbruggen, S. W., & Lenaerts, S. (2021). Challenges in the use of hydrogen for maritime applications. Energy & Environmental Science, 14(2), 815–843. https://doi.org/10.1039/D0EE01545H
Wang, Y., & Wright, L. A. (2021). A comparative review of alternative fuels for the maritime sector: Economic, technology, and policy challenges for clean energy implementation. World, 2(4), 456–481. https://doi.org/10.3390/world2040029
Wang, Y., Xiao, X., & Ji, Y. (2025). A review of LCA studies on marine alternative fuels: Fuels, methodology, case studies, and recommendations. Journal of Marine Science and Engineering, 13(2), 196. https://doi.org/10.3390/jmse13020196
Wei, H., Müller-Casseres, E., Belchior, C. R. P., & Szklo, A. (2023). Evaluating the readiness of ships and ports to bunker and use alternative fuels: A case study from Brazil. Journal of Marine Science and Engineering, 11(10), 1856. https://doi.org/10.3390/jmse11101856
Wu, P., & Lin, C. (2025). Feasibility and cost-benefit analysis of methanol as a sustainable alternative fuel for ships. Journal of Marine Science and Engineering, 13(5), 973. https://doi.org/10.3390/jmse13050973
Yadav, A., & Jeong, B. (2022). Safety evaluation of using ammonia as marine fuel by analysing gas dispersion in a ship engine room using CFD. Journal of International Maritime Safety, Environmental Affairs, and Shipping, 6(2–3), 99–116. https://doi.org/10.1080/25725084.2022.2083295
Zamboni, G., Scamardella, F., Gualeni, P., & Canepa, E. (2024). Comparative analysis among different alternative fuels for ship propulsion in a well-to-wake perspective. Heliyon, 10(4), e26016. https://doi.org/10.1016/j.heliyon.2024.e26016
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